Synthetic Membranes and Membrane Separation Processes

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On the other hand, cross-linked polymers are almost insoluble in organic solvents.

Materials for next-generation molecularly selective synthetic membranes | Nature Materials

They do not soften with temperature increase and are known as thermosetting polymers. Polymer selection must be based on compatibility with membrane fabrication technology and intended application use. For example, the polymer may require a low affinity toward the permeate, while other times it may need to withstand harsh cleaning conditions due to membrane fouling.


  1. On Levinas?
  2. Matsuura, Takeshi 1997 Synthetic Membranes And Membrane Separation Processes.
  3. References.
  4. From Biological to Synthetic Membranes!
  5. Artificial Intelligence: Strategies, Applications, and Models Through SEARCH;
  6. CAA1 - Biomimetic membranes and uses thereof - Google Patents.
  7. Membrane technology.

Chain interactions, chain rigidity, functional group polarity, and stereoisomerism also need to be factored into polymer choice and organic membrane manufacturing. Inorganic Membranes Metallic membranes are made from sintering metal powders such as tungsten, palladium or stainless steel and then depositing them onto a porous substrate.

The main use of metallic membranes is for hydrogen separation with palladium and its alloy being the primary choice of material. One major disadvantage for metallic membranes is surface poisoning effect.

Ceramic membranes consist of metal aluminum or titanium and non-metal oxides, nitride, or carbide. They are generally used for highly acidic or basic environments due to inertness. The downside of ceramic membranes is the high sensitivity to temperature gradient, which leads to membrane cracking. Fouling is partly due to blocking or reduction in effective diameter of membrane pores, and partly due to the formation of a slowly thickening layer on the membrane surface.

The extent of membrane fouling depends on the nature of the membrane used and on the properties of the process feed.

Synthetic Membranes and Membrane Separation Processes

Secondly, a module design which provides suitable hydrodynamic conditions for the particular application should be chosen. Process feed pretreatment is also important. In biotechnological applications pretreatment might include prefiltration, pasteurisation to destroy bacteria, or adjustment of pH or ionic strength to prevent protein precipitation. When membrane fouling has occurred, backflushing of the membrane may substantially restore the permeation rate. This is seldom totally effective however, so that chemical cleaning is eventually required.

When a DC electric current is transmitted through a saline solution, the cations migrate toward the negative terminal, or cathode, and the anions toward the positive terminal, the anode. By adjusting the potential between the terminals or plates, the electric current and, therefore, the flow of ions transported between the plates can be varied.

Synthetic Membranes and Membrane Separation Processes

Electrodialysis can be applied to the continuous-flow type of operation needed in industry. Multi-membrane stacks can be built by alternately spacing anionic- and cationic-selective membranes.

Membrane Separation in Bioprocessing

This adversely affects the operation of membranes and can even damage or destroy them. Other problems in practical applications include membrane scaling by inorganics in feed solutions as well as membrane fouling by organics. Added control of the movement of the ions can be obtained by placing sheet-type membranes of cation- or anion-exchange material between the outer plates, as shown diagrammatically in Figure 1.

These sheets of cationselective resins and anion-selective resins permit the passage of the respective ions in the solution. Under an applied DC field, the cations and anions will collect on one side of each membrane through which they are transported and vacate the other side. The feed solution is introduced at four points: It enters at both upper end points to sweep directly through both electrode chambers and is introduced into the working chambers near either end.

The feed solution into the left side traverses depleted chambers and exits as depleted effluent at the right. The feed solution into the rightmost enriching cell flows in the other direction and exits as enriched effluent at the left side. Cell membranes and intracellular membranes, 2.

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Mucous membranes, 3. S-layer, 4. Serous membranes and mesothelia that surround organs, including: a The peritoneum that lines the abdominal cavity b The pericardium that surrounds the heart c The pleura that surrounds the lungs d The periosteum that surrounds bone e The meninges that surround the brain the dura mater, the arachnoid, and the pia mater Artificial membranes are used in: 1. Reverse osmosis, 2.

From Biological to Synthetic Membranes

Filtration microfiltration, ultrafiltration , 3. Pervaporation, 4. Dialysis, 5. Emulsion liquid membranes, 6. Membrane-based solvent extraction, 7. Membrane reactors, 8.